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投稿时间:2022-05-13 修订日期:2022-05-19
投稿时间:2022-05-13 修订日期:2022-05-19
中文摘要: 稀土是我国的战略资源,在国民经济中占据非常重要的地位。电解工艺是生产稀土金属与合金的主要工艺。废石墨是稀土电解的废料,每吨金属约产生50~100kg,每年由于稀土电解造成的稀土损失约6650吨。稀土废石墨中稀土含量约5%,有较大的回收价值。本文研究了稀土废石墨的浮选工艺,探讨了药剂添加比、浮选时间、液固比及搅拌速率对石墨收率的影响。结果表明:采用II代改良药剂,在液固比为15:1,药剂添加比例为9.5‰,浮选时间为3.5h,搅拌速率250rpm时,石墨回收率达到了85%,浮选效果较好。
Abstract:Rare earth is China"s strategic resource and occupies a very important position in the national economy. Electrolysis process is the main process of producing rare earth metals and its alloys. Waste graphite is the waste from rare earth electrolysis, which produces about 50~100kg per ton of metal, and the annual loss of rare earth melting salt caused by rare earth electrolysis is about 6,650 tons. The rare earth content of waste graphite is about 5%, which has great recycling value. In this paper, the flotation process of rare earth waste graphite was investigated, and the influences of agent addition ratio, flotation time, liquid-solid ratio and stirring rate on graphite yield were discussed. The results showed that the graphite recovery rate reached 85% by adding the two-generation modified agent and keeping the liquid-solid ratio at 15:1, the ratio of agent addition at 9.5 ‰, the flotation time at 3.5h, and the stirring rate at 250rpm, and the satisfied flotation result was obtained.
文章编号: 中图分类号: 文献标志码:
基金项目:郑州大学科研发展基金,25124510001
作者 | 单位 | |
陈喜平 | 郑州大学材料科学与工程学院 | chenxiping@zzu.edu.cn |
李娜 | 郑州大学材料科学与工程学院 | |
申振芳* | 郑州大学材料科学与工程学院 | 15638748908@163.com |
轩红伟 | 郑州大学材料科学与工程学院 | |
张凯 | 郑州大学材料科学与工程学院 | |
马卓 | 郑州大学材料科学与工程学院 |
引用文本:
陈喜平,李娜,申振芳,轩红伟,张凯,马卓.稀土废石墨的浮选工艺研究[J].有色金属(选矿部分),2023(4):38-43.
CHEN Xiping,LI Na,SHEN Zhenfang,XUAN Hongwei,ZHANG Kai,MA Zhuo.Research on the Flotation Process of Waste Graphite from Rare Earth Electrolysis[J].Nonferrous Metals(Mineral Processing Section),2023(4):38-43.
陈喜平,李娜,申振芳,轩红伟,张凯,马卓.稀土废石墨的浮选工艺研究[J].有色金属(选矿部分),2023(4):38-43.
CHEN Xiping,LI Na,SHEN Zhenfang,XUAN Hongwei,ZHANG Kai,MA Zhuo.Research on the Flotation Process of Waste Graphite from Rare Earth Electrolysis[J].Nonferrous Metals(Mineral Processing Section),2023(4):38-43.