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有色金属(选矿部分):2025,(11):50-59
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某低品位花岗岩型含锂瓷土矿锂云母回收及尾矿综合利用研究
徐晓衣, 孟庆波, 李双棵, 张辉, 刘牡丹
(广东省科学院资源利用与稀土开发研究所)
Research on the recovery of lithium mica and comprehensive utilization of tailings from a low-grade granite-type lithium-bearing porcelain clay ore
Xu Xiaoyi, Meng Qingbo, Li Shuangke, Zhang Hui, LIU Mudan
(Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences)
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投稿时间:2025-02-14    修订日期:2025-03-05
中文摘要: 含锂陶瓷土矿是近年来探明开采的超大型锂矿,主要矿物为云母、长石和石英,化学组成以含锂、富铝钾钠、低铁、高硅为特征,锂主要以锂云母和锂白云母的形式存在,脉石为长石和石英。对该矿样进行详细的工艺矿物学研究,查明其矿物组成及含量、有价元素赋存状态、主要矿物嵌布特征,在此基础上开展锂云母浮选和云母尾矿长石/石英分离试验研究。研究结果表明,含Li2O 0.28%的原矿,磨矿脱泥后以六偏磷酸钠作为抑制剂,使用高效云母捕收剂NM-1,经过一粗二精二扫闭路试验得到Li2O品位1.70%、回收率84.30%的锂云母精矿。锂云母尾矿采用酸性无氟长石/石英分离工艺,获得Al2O3含量为17.19%、K2O和Na2O合量为9.91%,白度为68.1%的长石产品,SiO2含量为99.78%、Fe2O3含量为0.006%,白度为90.4%的石英产品。开发利用锂资源的同时实现尾矿中长石、石英高值化综合利用。
中文关键词: 含锂瓷土矿  锂云母  长石  石英  综合利用
Abstract:Lithium-containing ceramic clay ore is a super-large lithium ore discovered and mined in recent years, mainly consisting of mica, feldspar, and quartz. Its chemical composition is characterized by lithium content, aluminum rich potassium sodium, low iron, and high silicon. Lithium mainly exists in the form of lithium mica and lithium muscovite, and the gangue is feldspar and quartz. Detailed process mineralogical research was conducted on the mineral sample to determine its mineral composition and content, occurrence state of valuable elements, and main mineral distribution characteristics. Based on this, lithium mica flotation and mica tailings feldspar/quartz separation experiments were carried out. The research results show that after grinding and desliming, sodium hexametaphosphate was used as an inhibitor, and efficient mica collector NM-1 was used. A lithium mica concentrate with Li2O grade of 1.70% and recovery rate of 84.30% was obtained from the raw ore containing 0.28% Li2O through a closed-circuit test consisting of one roughing-two concentration-two sweepin. The lithium mica tailings were separated using an acidic fluorine-free feldspar/quartz separation process to obtain feldspar products with Al2O3 content of 17.19%, K2O and Na2O content of 9.91%, and whiteness of 68.1%, as well as quartz products with SiO2 content of 99.78%, Fe2O3 content of 0.006%, and whiteness of 90.4%. Developing and utilizing lithium resources while achieving high-value comprehensive utilization of feldspar and quartz in tailings.
文章编号:     中图分类号:    文献标志码:
基金项目:国家重点基础研究发展计划(973计划)
引用文本:
徐晓衣,孟庆波,李双棵,张辉,刘牡丹.某低品位花岗岩型含锂瓷土矿锂云母回收及尾矿综合利用研究[J].有色金属(选矿部分),2025(11):50-59.
Xu Xiaoyi,Meng Qingbo,Li Shuangke,Zhang Hui,LIU Mudan.Research on the recovery of lithium mica and comprehensive utilization of tailings from a low-grade granite-type lithium-bearing porcelain clay ore[J].Nonferrous Metals(Mineral Processing Section),2025(11):50-59.

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